Product ID:CROFORM 44
MSDS Date:04/16/1992
FSC:3439
NIIN:00N048092
MSDS Number: BSWXB

STOODY CO

BOWLING GREEN, KY 42102-4997
US

Emergency Phone: 502-781-9777

Info Phone: 502-781-9777

Cage: 57965

STOODY CO

90032 BOWLING GREEN, KY 42102-9032 US

Telephone: 502-781-9777

Cage: 57965

IARC MONOGRAPHS ON

RTECS: 9999999ZZ

PULMONARY FIBROSIS

RTECS: 9999999ZZ

MAY ALSO APPEAR. EMPLOYEES EXPOS TO

RTECS: 9999999ZZ

DETECTION OF MANGANISM. STUDIES HAVE SHOWN THAT PROD

RTECS: 9999999ZZ

INCIDENCE OF LUNG CANCERS. CHROMATES MAY CAUSE

RTECS: 9999999ZZ

ALLERGIC SKIN RASH HAVE BEEN REPORTED. LONG TERM

RTECS: 9999999ZZ

PNEUMOCONIOSIS. STUDIES OF NICKEL REFINERY WORKERS

RTECS: 9999999ZZ

SHIELDING GASES SUCH AS ARGON, HELIUM & CARBON

RTECS: 9999999ZZ

CAN INJURE EYES & BURN SKIN. HEAT RAYS (INFRARED

RTECS: 9999999ZZ

CAN KILL. NOISE CAN DAMAGE HEARING.

RTECS: 9999999ZZ

LENS. AS RULE OF THUMB, START W/SHADE THAT IS TOO

RTECS: 9999999ZZ

WHICH GIVES SUFFICIENT VIEW OF WELD ZONE. PROVIDE

RTECS: 9999999ZZ

INCL ARM PROTECTORS, APRONS, HATS,

RTECS: 9999999ZZ

MANGANESE (SARA III)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: 0-2%

OSHA PEL 5 MG/M3 DUST, C

ACGIH TLV: 5 MG/M3 DUST

SILICON

CAS: 7440-21-3

RTECS: VW0400000

Fraction By Weight: 0-5%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

CHROMIUM (SARA III)

CAS: 7440-47-3

RTECS: GB4200000

Fraction By Weight: 20-40%

OSHA PEL 1 MG/M3

ACGIH TLV: 0.5 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

NICKEL (SARA III)

CAS: 7440-02-0

RTECS: QR5950000

Fraction By Weight: 0-5%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

MOLYBDENUM (INSOLUBLE COMPOUNDS)

CAS: 7439-98-7

RTECS: QA4680000

Fraction By Weight: 0-10%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3

IRON

CAS: 7439-89-6

RTECS: NO4565500

Fraction By Weight: 0-5.50%

OSHA PEL 10 MG/M3

ACGIH TLV: 5 MG/M3

TUNGSTEN; (TUNGSTEN,AS W,INSOLUBLE COMPOUNDS)

CAS: 7440-33-7

RTECS: YO7175000

Fraction By Weight: 0-15%

OSHA PEL 5 MG/M3;10 STEL

ACGIH TLV: 5 MG/M3;10 STEL

COBALT (SARA III) (DUST AND FUME)

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: 30-60%

OSHA PEL 0.1 MG/M3 (AS CO)

ACGIH TLV: 0.05 MG/M3 DUST

TUNGSTEN, IRON. GASEOUS RXN PRODS MAY INCL CARBON

RTECS: 9999999ZZ

BE FORMED BY THE RADIATION FROM THE ARC.

RTECS: 9999999ZZ

LUNG CANCER, SKIN ULCERS.

RTECS: 9999999ZZ

GRP 2B. NTP 6TH

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:OVEREXP TO WELDING FUMES MAY
RSLT IN DISCOMFORT SUCH AS:DIZZ, NAUS OR DRYNESS/IRRIT OF NOSE,
THROAT/EYES. CHROMATES PRESENT IN FUME CAN CAUSE IRRIT OF RESP SYS,
DMG TO LUNGS & ASTHMA LIKE SYMPS. NICKEL CMPDS IN FUME CAN CAUSE
METALLIC TASTE, NAUS, TIGHTNESS IN CHEST, FEVER & ALLERGIC RXNS.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:CHROMIUM:IARC MONOGRAPHS, VOL 49, PG 49,
1990:GRP 1. NTP 6TH ANNUAL RPT ON CARCINS, 1991:KNOWN TO BE CARCIN.
(ING 11)
Effects of Overexposure:HLTH HAZ:FLUORIDES CAN CAUSE PULM EDEMA BRONCH.
CHRONIC:OVEREXP TO WELDING FUMES CAN LEAD TO SIDEROSIS (IRON
DEPOSITS IN LUNG) & AFFECT PULM FUNC. LONG TERM OVEREXP TO
MANGANESE CMPDS MAY AFFECT CNS. SYMPS INCL MUSCULAR WEAK & TREMORS
SIMILAR TO PARKINSON'S DISEASE. BEHAVIORAL CHANGES & CHANGES IN
HANDWRITING (ING 15)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:CALL FOR MEDICAL AID. EMPLOY FIRST AID TECHNIQUES RECOMMENDED
BY AMERICAN RED CROSS. INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO
FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:I
MMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK
ASSISTANCE FROM MD . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD
.

Flash Point:NONFLAMMABLE
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:WELDING ARC & SPARKS CAN IGNITE
COMBUSTIBLES & FLAMMABLES. REFER TO ANSI Z49.1 FOR FIRE PREVENTION
DURING USE OF WELDING & ALLIED PROCEDURES.

Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:TRAIN WELDER NOT TO TOUCH LIVE ELEC
PARTS & TO INSULATE HIMSELF FROM WORK & GROUND. TRAIN WELDER TO
KEEP HIS HEAD OUT OF FUMES.
Other Precautions:READ & UNDERSTAND MFR'S INSTRUCTIONS & PREC LBL ON
PROD. SEE ANSI Z49.1, SFTY IN WELDING & CUTTING PUBLISHED BY AWS,
P.O. BOX 351040, MIAMI, FL 33135 & OSHA PUB 2206 (29CFR1910). US
GOVT PRINTING OFC, WASHINGTON, D.C. 20402 FOR MORE DETAIL.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRABLE FUME
RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED
SPACE/WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE
BELOW TLV.
Ventilation:USE ENOUGH VENT, LOCAL EXHAUST AT THE ARC, OR BOTH TO KEEP
FUMES & GASES BELOW TLV IN WORKER'S BRTHG ZONE & GEN AREA.
Protective Gloves:WELDER'S GLOVES.
Eye Protection:WEAR HELMET/USE FCSHLD W/FILTER (ING 23)
Other Protective Equipment:WEAR HEAD, HAND & BODY PROT WHICH HELPS TO
PVNT INJURY FROM RADIA, SPKS & ELEC SHOCK. SEE ANSI Z49.1, THIS MAY
(ING 25)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
HAZ DECOMP PROD:USED, COATINGS, NUMBER OF WORKERS, CONTAMS IN ATM.
FUMES & GASES MAY VARY IN FORM & PERCENT FROM INGS LISTED. REAS
EXPECTED FUME CONSTITUENTS OF THESE PRODS WOULD INCL:PRIMARILY
COMPLE X OXIDES OF COBALT, CHROMIUM & NICKEL; SECONDARILY COMPLEX
OXIDES OF MANGANESE, SILICON, BORON, MOLYBDENUM, (ING 9)

Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:COMPOSITION & QTY OF FUMES & GASES ARE
DEPENDENT UPON METAL BEING WELDED, PROCESS, PROC, ELECTRODES USED,
GASES (SUPDAT)

Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR
LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE
W/FEDERAL, STATE & LOC AL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.